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https://www.cnet.com/news/why-is-samsung-galaxy-note-7-exploding-overheating/

Here's why Samsung Note 7 phones are catching fire

You plug your smartphone into the bedside charger and place it on your nightstand with care.

You wake to find your nightstand in flames, smoke billowing everywhere.

Or maybe your Jeep. Your hotel room. Your entire home.

How could this have happened? Simple: your phone is a Samsung Galaxy Note 7 -- and it's one of over a hundred that have spontaneously burst into flames.

After 35 reported incidents of overheating smartphones worldwide, Samsung made the unprecedented decision to recall every single one of the Galaxy Note 7 smartphones sold. That's said to be 1 million of the 2.5 million that were manufactured. (Since the recall was first announced, the number of explosive Note 7s has nearly quadrupled.)

The company stopped all sales and shipments of the Note 7, worked with government agencies and cellular carriers around the world to provide refunds and exchanges for the phone, and apparently it still wasn't enough: As of October 10, as many as five of the supposedly safe replacement Note 7 phones have caught fire as well, and Samsung is asking all users to shut down their phones.

Once again, every US carrier has halted sales of the Samsung Galaxy Note 7, and a second recall may be nigh. We're not sure why the new batteries might have caught fire, as Samsung told us they'd be brand-new.

But why did these phones even catch fire to begin with?

Here's what we know about Samsung's battery woes.

The basics
The science behind phone battery fires is actually pretty simple, and fairly well understood. Much like the infamous exploding hoverboards, phones use lithium ion battery packs for their power, and it just so happens that the liquid swimming around inside most lithium ion batteries is highly flammable.

If the battery short-circuits -- say, by puncturing the incredibly thin sheet of plastic separating the positive and negative sides of the battery -- the puncture point becomes the path of least resistance for electricity to flow.

It heats up the (flammable!) liquid electrolyte at that spot. And if the liquid heats up quickly enough, the battery can explode.

The Galaxy Note 7 certainly isn't the first phone to catch on fire, or even the first giant recall. By 2004, a spike in cell phone battery explosions prompted this CNET article. In 2009, Nokia recalled 46 million phone batteries that were at risk of short-circuiting. Exploding phones have even allegedly killed people.

No brand or model is necessarily safe: for instance, unlucky iPhone owners allegedly suffered nasty burns from exploding devices in 2015 and 2016. And though the Galaxy Note 7 is making headlines right now, other Samsung phones have also burst into flames, like the Galaxy Core that allegedly burned a 6-year-old child earlier this week.

We've known for years that lithium ion batteries pose a risk, but the electronics industry continues to use the flammable formula because the batteries are so much smaller and lighter than less-destructive chemistries. Lithium ion batteries pack a punch, for better or for worse.

Statistically small
Just because a simple phone could turn into a destructive inferno doesn't mean that it will -- even if it's a new Galaxy Note.

According to an unnamed Samsung official who spoke to Yonhap News, the Note 7's manufacturing defect affects less than 0.01 percent of all Note 7 handsets sold. Some quick back-of-the-envelope math, and you're potentially looking at fewer than 1,000 defective phones. "It is a very rare manufacturing process error," a Samsung rep told CNET.

But it's the damage those phones can cause, and the frequency with which they're causing damage, that makes the Note 7 dangerous.

While CNET tends to hear about just a few exploding devices each year, Samsung's Galaxy Note 7 has caught fire as many as 112 times after only one month on sale.

(That's based on official tallies of 92 incidents in the US, plus at least 17 in Korea, 1 in Taiwan and 2 in Australia.)

Update, September 15 at 2:00p.m. PT: Updated tally with official US incident count from the Consumer Product Safety Commission.

Why Note 7?
What makes the Note 7 different: Samsung may have accidentally squeezed its batteries harder than it should.

According to a unpublished preliminary report sent to Korea's Agency for Technology and Standards, Samsung had a manufacturing error that "placed pressure on plates contained within battery cells," which "brought negative and positive poles into contact."

"The defect was revealed when several contributing factors happened simultaneously, which included sub-optimized assembly process that created variations of tension and exposed electrodes due to insufficient insulation tape," a Samsung representative tells CNET.

Or, in plain English: the thin plastic layer that separates the positive and negative sides of the battery got punctured, became the shortest route for electricity to zap across the battery (that's why they call it a "short-circuit"), and became a huge fire risk.

What does pressure have to do with it? MIT materials chemistry Professor Don Sadoway explains that today's cell phone batteries are made by literally pressing together a stack of battery components -- and that battery companies are under pressure (no pun intended) to cram in as much battery capacity as possible.

"Imagine if you had a toilet paper roll and it wasn't packed tightly," says Sadoway. With the same size roll, you'd run out a lot quicker.

At first, Sadoway has two theories: perhaps Samsung simply pressed so hard that the positive and negative terminals poked right through the separator and managed to touch.

Or perhaps it's the sponge-like separator itself that got squished. Normally, says Sadoway, the separator allows the liquid electrolyte to pass through pores connecting the negative and positive sides of the battery, even as it keeps the two terminals separate. "If they press really hard, they constrict the pores, the resistance goes up and you generate more heat," says the professor.

But there's another, more interesting theory: perhaps Samsung's batteries are skewering themselves on their own tiny spears.

Why didn't the phones catch fire immediately?
When Sadoway explains these theories, one thing doesn't seem to add up. Today's cell phone batteries generally charge faster (and get hotter) when they're first plugged into the wall, not at the end when they're trickle-charging the last few percent to reach their maximum capacity.

But these Note 7 phones didn't explode right away. In practically every reported instance of a Note 7 catching fire or exploding, it happened after the phone was plugged in and left charging, sometimes overnight.

Then, there's the little matter of how Samsung plans to make these phones safer -- by issuing a firmware update that keeps the Galaxy Note 7 from charging to more than 60 percent of its full capacity. How could that possibly help, if things heat up the moment a phone is plugged into the wall?

Sadoway has a theory -- albeit one without proof. What if only part of the battery was squished improperly, so that the phone couldn't tell when it was 100 percent charged, and kept on charging the cell?

When lithium ion batteries are continually trickle charged, the lithium ions can start to cover the surface of the negative contact in a coating of lithium metal through a process called "plating." And in extreme conditions, that lithium metal can form tiny spikes (called "dendrites") that can poke right through the separator, creating -- you guessed it -- a short circuit.

That would seem to line up with the "variations in tension" Samsung says it found inside the defective battery cells.

"My guess is by backing off to 60 percent charge, they'll be well below the threshold where these things happen," says Sadoway. "Imagine we're trying to fill our gas tank, we don't have a really good regulator, and we don't want to spill the gas all over our shoes. We want to make sure we're cutting off the flow well before this thing gets to overflow conditions."

Samsung didn't respond when asked for comment on the theory.

What happens next
These are just a few theories based on one battery expert's remote analysis of Samsung's initial findings. We don't have the whole truth yet, and the truth is what Samsung and government agencies around the world are looking for as we speak. Just one mystery: why the replacement batteries might also be exploding.

We'd confirmed that the replacement Notes had a battery from a different supplier -- the manufacturing issues were found in batteries built by Samsung SDI -- but maybe that wasn't enough.

Anyhow, organizations like the US Consumer Product Safety Commission have officially stepped in to recall the Galaxy Note 7 and figure out what happened, and they may recall it again.

But that could take time. It took six months for the CPSC to complete its investigation into hoverboard battery fires, to give you some idea.

#samsung #tech #fire #epicfail